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DIALLYLETHER BISPHENOL A

Bisphenol-A diallyl ether

CAS: 3739-67-1

Molecular Formula: C21H24O2

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DIALLYLETHER BISPHENOL A - Names and Identifiers

Name Bisphenol-A diallyl ether
Synonyms BBE
223-123-3
DIALLYLETHER BISPHENOL A
Bisphenol-A diallyl ether
Bisphenol A diallyl ether
Bisphenol A bisallyl ether
Bisphenol A Bisallyl Ether
PARA-DIALLYL ETHER BISPHENOL-A
2,2-Bis(4-allyloxyphenyl)propane
Propane, 2,2-bis(p-(allyloxy)phenyl)-
Propane, 2,2-bis[p-(allyloxy)phenyl]-
4,4'-isopropylidenebis[(allyloxy)benzene]
1,1'-Propane-2,2-diylbis[4-(allyloxy)benzene]
1,1'-propane-2,2-diylbis[4-(prop-2-en-1-yloxy)benzene]
1,1'-(1-Methylethylidene)bis[4-(2-propenyloxy)benzene]
3,3'-[Dimethylmethylenebis(4,1-phenyleneoxy)]bis(1-propene)
benzene, 1,1'-(1-methylethylidene)bis[4-(2-propen-1-yloxy)-
CAS 3739-67-1
EINECS 223-123-3
InChI InChI=1/C21H24O2/c1-5-15-22-19-11-7-17(8-12-19)21(3,4)18-9-13-20(14-10-18)23-16-6-2/h5-14H,1-2,15-16H2,3-4H3

DIALLYLETHER BISPHENOL A - Physico-chemical Properties

Molecular FormulaC21H24O2
Molar Mass308.41
Density1.043 g/cm3(Temp: 25 °C)
Boling Point125-180 °C
Flash Point155.3°C
Vapor Presure3.25E-07mmHg at 25°C
Storage ConditionRoom Temprature
Refractive Index1.536
UseMainly used for the crosslinking agent of epoxy resin

DIALLYLETHER BISPHENOL A - Reference

Reference
Show more
1. [IF=3.645] Guiqi Huang et al."Evaluation of three sorbent-phase extraction techniques based on hyper-crosslinked polymer for the extraction of five endocrine disrupters in water."Journal Of Separation Science. 2021 Dec 16

DIALLYLETHER BISPHENOL A - Reference Information

EPA chemical information Information provided by: ofmpub.epa.gov (external link)
overview bisphenol A bisallyl ether is an important organic synthesis intermediate, mainly used for crosslinking agent of epoxy resin. At present, most methods for synthesizing bisphenol A bisallyl ether are to first add bisphenol A and alkali to the solvent to react to form bisphenol A salt, and then add allyl halide for etherification to obtain the product. This requires the use of additional solvents. The recovery of solvents not only increases the cost, but also most of the solvents used are harmful to the environment. The existing technology uses ethanol as a solvent, and uses bisphenol A, sodium hydroxide, and propylene chloride as raw materials to synthesize bisphenol A bisallyl ether. Although the method uses ethanol as a solvent, although it is relatively environmentally friendly, water will be produced in the reaction, which makes it difficult to reuse ethanol, and excessive chloropropene will react with ethanol to form chloropropene ether. The product synthesized by this method has a darker color and needs to be washed with toluene, and activated carbon adsorption can obtain qualified products, which virtually increases the amount of solvent used. In the prior art, toluene and diallyl ether are used as solvents, and allyl alcohol is allowed to react with bisphenol A under catalyst conditions to obtain bisphenol A bisallyl ether. This method will produce many by-products, and the yield is very low.
application bisphenol A bisallyl ether can be rearranged to form diallyl bisphenol A under high temperature or catalyst conditions. diallyl bisphenol A is an excellent modifier of bismaleimide (BMI) resin, which can greatly reduce the application cost of BMI resin and improve the operability and manufacturability of BMI resin. BMI resin is widely used in aviation, aerospace, machinery, electronics and other industries with its excellent performance, and its dosage is very large. In addition, bisphenol A bisallyl ether can also be applied to adhesives on the surface of semiconductor wafers, photoresist materials, impact-resistant prepregs, fiber-reinforced structural parts molding, high-temperature and chemical corrosion-resistant mixed materials, etc. Therefore, bisphenol A bisallyl ether has great commercial development value.
preparation method 1: a synthesis method of bisphenol A bisallyl ether, which comprises the following steps: adding 228g bisphenol A, 112gKOH, 114g bisphenol A bisallyl ether into the reaction kettle, starting stirring, vacuuming with a vacuum pump, replacing the air in the reaction kettle with N2, adding 0.114g of reduced Fe powder and 367.5g of allyl chloride into the reaction kettle after N2 is placed, closing the reaction kettle, heating to 110 ℃ for 3 hours. After the reaction is over, 68.4g of deionized water is added into the reaction kettle, stirred for 10min, let stand and layer in layers, release the lower layer of water after being divided into layers, and repeat for many times until the separated water phase is neutral. The upper organic phase is dehydrated under reduced pressure and filtered to obtain the final product. The obtained product has 95.3% purity and color 17.
use mainly used as crosslinking agent for epoxy resin
bisphenol A bisallyl ether is applied to high-end application technology, including adhesive on the surface of semiconductor wafer, photoresist material, impact prepreg, forming of fiber reinforced structural parts, mixed materials for preventing high temperature and chemical corrosion, high temperature coating, waterproof, anti-corrosion and other functions
Last Update:2024-04-10 22:29:15
DIALLYLETHER BISPHENOL A
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Email: 3008007409@qq.com
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DIALLYLETHER BISPHENOL A
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